• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Pipe or coated tank element (10) comprising a ductile iron, steel or concrete pipe or pipe element (12) and an inner liner (18) on an inner wall (14) of the pipe element or crude tank, the inner coating being obtainable by application to the inner wall of a mortar comprising a binder. The binder comprises one of: a first composition comprising a mixture of CEM I SR Portland cement and blast furnace slag, the mass proportion of CEM I SR Portland cement in said mixture being between 5% and 64%; a second composition comprising a mixture of CEM III / B cement and microsilica, or a mixture of CEM I SR Portland cement and microsilica, the mass proportion of CEM III / B cement or Portland CEM I SR cement in said mixture being between 50% and 94%, and the mixtures of the first composition and the second composition.
    公开号:FR3080904A1
    申请号:FR1853916
    申请日:2018-05-07
    公开日:2019-11-08
    发明作者:Cyril Guerandel；Joêl FRANOIS-BRAZIER
    申请人:Saint Gobain PAM SA；
    IPC主号:
    专利说明:

    Pipe or tank element with internal cement coating
    The present invention relates to a coated pipe or tank element comprising a raw pipe or tank element of ductile iron, steel or concrete, and an inner lining located on an inner wall of the raw pipe or tank element , the interior coating being capable of being obtained by application to the interior wall of a mortar comprising a binder.
    These elements form, for example, pipes or tanks intended for the supply, distribution or storage of drinking water.
    Cementitious materials are likely to be degraded during prolonged contact with water. This phenomenon takes place by dissolving certain elements of the cement matrix, thus enriching the liquid in contact with the material with minerals. This dissolution process reduces the durability of the material, because it depletes part of the cement matrix of its constituent elements and mainly of its calcium. This leads to the appearance of a degradation layer, the thickness of which depends on both the type of cement composition and the time of exposure to the liquid.
    In order to reduce this degradation phenomenon, the applicant uses a slag cement, known as CEM III / B according to standard NF EN 197-1, in its version of April 2012. This cement is defined as comprising by mass between 20% and 34% clinker, 66% to 80% blast furnace slag, and 0% to 5% adjuvant (s). Such a coating has excellent durability properties and makes it possible to reduce the degraded thickness compared to a Portland cement known as CEM I.
    However, this coating sometimes releases aluminum, in a non-negligible amount in the liquid in contact with it.
    Aluminum is a naturally occurring element in the environment, in soils and waters, including those intended for human consumption. However, due to its potential toxicity, it is desirable to reduce human exposure to aluminum.
    Thus, an object of the invention is to provide a pipe or reservoir element coated with a cementitious material releasing less aluminum into the water, while retaining good mechanical properties and durability.
    To this end, the invention relates to a coated pipe or reservoir element of the above type, in which the binder comprises one of:
    a first composition comprising a mixture of Portland cement CEM I SR and blast furnace slag, the mass proportion of Portland cement CEM I SR in said mixture being between 5% and 64%,
    a second composition comprising a mixture of CEM III / B cement and microsilica, or a mixture of Portland cement CEM I SR and microsilica, the mass proportion of CEM III / B cement or Portland cement CEM I SR in said mixture being between 50% and 94%, and
    - mixtures of the first composition and the second composition.
    According to particular embodiments, the coated pipe or tank element comprises one or more of the following characteristics, taken alone or in any technically possible combination:
    the binder comprises a mixture of Portland CEM I SR cement, slag and microsilica, the mass proportion of Portland CEM I SR cement in said mixture being between 30% and 60%, preferably between 40% and 60%, and even more preferably between 50% and 60%, the proportion by mass of the slag in said mixture being between 65% and 5%, preferably between 50% and 10%, and even more preferably between 30% and 10% , and the proportion by mass of microsilica in said mixture being between 5% and 35%, preferably between 10% and 30%, and even more preferably between 20% and 30%;
    - Portland cement CEM I SR of the first composition or of the second composition or of their mixtures is a CEM I SR5, preferably a CEM I SR3, and even more preferably a CEM I SR0;
    - The mass proportion of Portland cement CEM I SR in said mixture of the first composition is between 20% and 64%, preferably between 25% and 50%, and even more preferably between 25% and 34%;
    - The mass proportion of CEM III / B cement or Portland CEM I SR cement in said mixture of the second composition is between 60% and 90%, preferably between 70% and 80%;
    - The mortar also comprises fillers, in a mass ratio (S / L) relative to the binder of between 0.5 and 5, preferably between 1 and 4, and even more preferably between 1.5 and 3;
    the fillers are filler, sand and / or gravel, preferably of a siliceous or calcareous nature, at least 95% by mass of the fillers having a diameter less than or equal to 8 mm,
    the mortar also comprises water, in a mass ratio (W / L) of water relative to the binder of between 0.2 and 1, preferably between 0.3 and 0.5, and so even more preferred between 0.35 and 0.45;
    the binder comprises the first composition, and the mortar also comprises one or more superplasticizer (s), in a mass ratio (Sp / L) of superplasticizer (s) relative to the binder of between 0.0005 and 0.1, preferably between 0.001 and 0.05, and even more preferably between 0.002 and 0.03, or the binder comprises the second composition, and the mortar further comprises one or more superplasticizer (s), in a mass ratio (Sp / L) of superplasticizer (s) with respect to the binder of between 0.005 and 0.1, preferably between 0.001 and 0.08, and even more preferably between 0.005 and 0.05;
    - Said one or more superplasticizer (s) comprises a polycarboxylate solution with a dry extract of 10% to 50%, preferably from 20% to 40% and even more preferably from 25% to 35%; and
    the mortar also comprises one or more adjuvant (s), in a mass ratio (A / L) of adjuvant (s) relative to the binder of between 0.001 and 0.05, preferably between 0.005 and 0.04, and even more preferably between 0.01 and 0.03.
    By "filler" (from English to fill, which means fill), we mean for example fines, or addition fines, that is to say a fine aggregate.
    The invention also relates to a pipe or a tank comprising coated pipe or tank elements as described above, the pipe or the tank being for example intended for the supply, distribution or storage of drinking water. .
    The invention will be better understood on reading the description which follows, given solely by way of example and made with reference to the appended drawings, in which:
    FIG. 1 is a cross-sectional view of a coated pipe element according to the invention which can, if necessary, be used to form a reservoir,
    FIG. 2 is a graph showing the results of aluminum leaching tests on monolithic samples of hardened cement pastes produced according to standard EN 7345, and comparing two formulations according to the invention with a reference formulation,
    - Figures 3 to 5 are also graphs showing the results of aluminum migration tests carried out according to standard EN 14944-3 on pipe cuts, respectively for a reference coating and two coatings according to the invention.
    Referring to Figure 1, there is described a pipe 1, advantageously buried, suitable for transporting or storing a liquid 5, for example drinking water. Line 1 includes a coated line element 10, and other coated line elements not shown.
    The coated pipe element 10 comprises a raw pipe element 12 made of ductile iron, steel or concrete, defining an interior wall 14 and an exterior wall 16, an interior coating 18 located on the interior wall, and optionally an exterior coating 20 located on the outer wall. The coated pipe element 10 defines an interior space 22 in which the liquid 5 circulates in contact with the interior coating 18.
    The raw pipe element 12 is for example a pipe, a branch or forms a reservoir.
    The external coating 20 is advantageously suitable for contact with a ground 24. The external coating 20, known in itself to those skilled in the art, is advantageously configured to increase the corrosion resistance of the raw pipe element 12.
    The interior covering 18 advantageously lines the entire interior wall 14.
    In the example shown, the interior coating 18 is obtained by applying to the wall 14 a mortar comprising a cement-based binder. The application is advantageously carried out by centrifugation, but can also be done by spraying or by manual coating.
    The internal coating 18 advantageously has a thickness E for example between 3 mm and 30 mm.
    In addition to the binder, the mortar includes fillers, water, one or more superplasticizers, and one or more other additives.
    According to a first embodiment, the binder comprises a first composition comprising a mixture of Portland cement CEM I SR and blast furnace slag. Advantageously, this first composition consists of this mixture.
    Portland cement CEM I SR is known in itself to those skilled in the art and for example defined in the French and European standard NF EN 197-1 of April 2012. This cement contains, by mass, 95% to 100% clinker, and 0% to 5% of minor additional constituents. The cement is said to be SR 0, SR 3 or SR 5 depending on whether it contains 0% by mass, less than 3% or less than 5% of C3A respectively, that is to say tricalcite aluminate. In other words, Portland cement CEM I SR is a Portland cement CEM I in which the mass proportion of C3A is less than or equal to 5% by mass.
    The mass proportion of Portland cement CEM I SR in said mixture of the first composition is between 5% and 64%, the rest being slag.
    The Portland cement CEM I SR used is a CEM I SR5, preferably a CEM I SR3, and even more preferably a CEM I SR0, that is to say that it contains a mass proportion of C3A less than or equal at 5%, preferably less than or equal to
    3%, and even more preferably 0%. C3A can nevertheless be present in trace amounts in CEM I SRO cement, that is to say in an amount less than 0.1% by mass of cement, in principle undetectable by X-ray diffraction.
    Advantageously, the mass proportion of Portland cement CEM I SR in said mixture of the first composition is between 20% and 64%, preferably between 25% and 50%, and even more preferably between 25% and 34%.
    Advantageously, the fillers of the mortar are sand, gravel, or their mixtures. Preferably, the sand and gravel are of a siliceous or calcareous nature. Advantageously, at least 95% by mass of the fillers have a diameter less than or equal to 8 mm. The diameter is for example measured according to the standard NE EN 933-1 of May 2012, thanks to the test for determining the geometrical characteristics of the aggregates Partial: Determination of the granularity - Size analysis by sieving. Advantageously, the particles are in a mass ratio S / L relative to the binder of between 0.5 and 5, preferably between 1 and 4, and even more preferably between 1.5 and 3.
    In the mortar, the water is advantageously in a mass ratio W / L relative to the binder of between 0.2 and 1, preferably between 0.3 and 0.5, and even more preferably between 0.35 and 0.45.
    The role of the superplasticizer (s) is in particular to increase the fluidity of the mortar at constant water dosage, or to decrease the water content at constant fluidity. The superplasticizer (s) are for example in a mass ratio Sp / L relative to the binder of between 0.0005 and 0.1, preferably between 0.001 and 0.05, and even more preferably between 0.002 and 0.03. Advantageously, the mortar comprises a single superplasticizer, for example a polycarboxylate solution, with a dry extract advantageously between 10% and 50%, preferably between 20% and 40%, and even more preferably between 25% and 35% .
    Advantageously, the adjuvant (s) are in a mass ratio A / L relative to the binder of between 0.001 and 0.05, preferably between 0.005 and 0.04, and even more preferably between 0.01 and 0.03.
    The additives are organic or mineral. Examples include setting (or hardening) accelerators, setting retarders and viscosity modifiers.
    According to a second embodiment, the mortar binder comprises a second composition comprising a mixture of CEM III / B cement with microsilica (or silica fume) or a mixture of Portland CEM I SR cement with microsilica.
    The mass proportion of CEM III / B cement or Portland CEM I SR cement in said mixture of the second composition is between 50% and 94%, the rest being microsilica. Advantageously, the mass proportion of the cement in the second composition is between 60% and 90%, and preferably between 70% and 80%.
    In the second embodiment, the other components of the mortar (water, fillers, superplasticizers and adjuvants) are unchanged and the remarks concerning them made above for the first embodiment apply.
    The second embodiment is advantageously implemented with a higher Sp / L mass ratio relative to the binder: for example between 0.005 and 0.1, preferably between 0.001 and 0.08, and even more preferably between 0.005 and 0.05.
    According to a third embodiment, the mortar binder consists of a mixture of the first composition and the second composition as described above, in respective arbitrary proportions.
    Advantageously, according to this third embodiment, the binder comprises a mixture of Portland cement CEM I SR, slag and microsilica.
    The mass proportion of Portland CEM I SR cement in the mixture is for example between 30% and 60%, that of slag between 65% and 5% and that of microsilica between 5% and 35%. Preferably, the mass proportion of Portland cement CEM I SR is between 40% and 60%, that of slag between 50% and 10% and that of microsilica between 10% and 30%. Even more preferably, in this mixture, the mass proportion of Portland cement CEM I SR is between 50% and 60%, that of slag between 30% and 10% and that of microsilica between 20% and 30%.
    Thanks to the characteristics described above, the internal coating 18 makes it possible to reduce the release of aluminum into the liquid 5.
    For the first embodiment, without being bound to a particular theory, the inventors believe that reducing the formation of ettringite (of formula Ca 6 AI 2 (SO4) 3 (OH) 12 .26H2O) by reducing the C3A contents by the Portland cement fraction makes it possible to significantly reduce the salting out of aluminum, although this element is mainly contained in the slag (10% AI2O3), one of the constituents of the binder.
    For the second embodiment, without being bound to a particular theory, the inventors also believe that the use of microsilica in combination with Portland cement CEM I SR or CEM cement III / B also makes it possible to limit the formation of ettringite and significantly reduce the release of aluminum.
    Ettringite contributes to the setting and hardening of cements. However, the use of the centrifugation process to produce the internal coating 18 makes it possible, surprisingly, to overcome the constraints of setting / hardening and leads to adequate mechanical performance, in particular a mechanical resistance in compression greater than or equal to 50 MPa 28 days (according to EN 545).
    In addition, thanks to the first composition, the durability of the interior coating 18 is equivalent to or better than that of a standard cement-based coating CEM III / B. CEM III / B cement typically comprises, by mass, between 20% and 34% of clinker, 66% to 80% of blast furnace slag, and 0% to 5% of minor additional constituents.
    Compared with CEM III / B cement, the new binder according to the first composition makes it possible to reduce the dosages of superplasticizer necessary to achieve the fluidity adequate for the implementation of the coating.
    Thanks to the second composition, the durability of the interior coating 18 is significantly higher than that of a coating made from Portland cement, and of the same order of magnitude as that of a coating made with only CEM III / B without microsilica.
    Experimental results
    A - Tests on hardened cement pastes
    10 cm edge cubes were made from cement paste and cured for 28 days at 100% humidity, before being exposed to a leaching test in accordance with EN 7345 of March 1995 , titled Leaching Characteristics of Building Materials and Compacted Earth and Stone Waste. Leaching tests. The standard proposes a determination of the leaching of anorganic compounds in shaped and monolithic materials by means of a diffusion test, used for the present tests.
    The mass quantities of dry matter of the binder formulations tested are presented in Table 1 below.
    CEM lll / B CEM I SR0 Dairy microsilica Reference 100% - - - Example 1 - 30% 70% - Example 2 - 75% - 25%
    Table 1: Mass quantities of dry matter for the formulations of binders tested according to standard EN 7345.
    In the so-called reference formulation, the binder used is a CEM III / B cement comprising 9.7% of alumina by mass. In all the formulations tested, the water / binder ratio is equal to 0.31.
    Example 1 is in accordance with the first composition described above, with a binder comprising by mass 30% Portland cement CEM I SR0 and 70% blast furnace slag. Such a binder comprises 8.7% by mass of alumina.
    Example 2 is in accordance with the second composition, with a binder comprising, by mass, 75% of Portland cement CEM I SR0 and 25% of microsilica. It is densified silica smoke from Elkem. Such a binder comprises 2.7% by mass of alumina. In Example 2, the paste also comprises 0.45% by mass of an Optima 220 superplasticizer from the company Chryso.
    The results of the aluminum leaching tests are presented in Figure 2. They provide the cumulative quantities of leached aluminum, in milligrams / m 2 (in standard EN 7345 the leached contents are expressed per unit area, more precisely by square meter of hardened cement paste, depending on the square root of the time expressed in hours). Curve C0 relates to the reference cube, while curves C1 and C2 relate respectively to Example 1 and Example 2.
    Table 2 below summarizes the reduction in aluminum leaching obtained for the new formulations (Examples 1 and 2) compared to the CEM III / B cement-based reference formula. In addition, the durability of the binders has been expressed as the ability to reduce the leaching of calcium compared to an ordinary Portland CEM I cement (that is to say comprising more than 5% by mass of C3A).
    CEM lll / B Example 1 Example 2 Reduced aluminum leaching (compared to CEM lll / B) 0% 40% 87.5% Reduced calcium leaching (compared to CEM I) 57% 68% 45%
    Table 2: Reduction of aluminum leaching from new formulations and reduction of calcium leaching.
    As can be seen, examples 1 and 2 made it possible to reduce the leaching of aluminum by 40% and 87.5% respectively, after 1536 hours or 64 days.
    In addition, calcium leaching was reduced by 68% and 45% respectively compared to ordinary Portland CEM I cement. This demonstrates that the hardened binder cubes obtained from the first composition and the second composition are more durable than the binders obtained from ordinary Portland cement.
    B - Tests on prototype pipes
    Coatings based on the different formulations of binders were deposited in cast iron pipes by a centrifugation process known in itself. The coating formulations are presented in Table 3 below.
    CEM lll / B CEM I SRO Dairy microsilica Sand 0-2 mm superplasticizer Reference 37.7 kg 62.3 kgExample 111.3 kg 26.4 kg62.3 kgExample 228.2 kg9.36 kg 62.07 kg 0.37 kg
    Table 3: Mass quantities of materials for the mortar formulations used to make prototype pipes.
    As can be seen, the reference coating contains 37.7% CEM lll / B cement and 62.3% sand with a particle size between 0 and 2 mm. The coating before solidification also includes water in a water / binder ratio of 0.46.
    Example 1 is a mortar according to the first embodiment, comprising, by mass, 11.3% of Portland cement CEM I SRO, 26.4% of blast furnace slag, and 62.3% of sand of particle size 0 at 2 mm. The water / binder ratio is 0.50.
    Example 2 is a mortar according to the second embodiment, comprising, by mass, 28.3% of Portland cement CEM I SRO, 9.4% of microsilica 940D, and 62.3% of sand with particle size 0 to 2 mm. Example 2 also comprises 1% of Optima 220 Chryso superplasticizer relative to the mass of binder. The water / binder ratio is 0.46 in this example.
    The mechanical properties of the mortars in the fresh or hardened state were determined respectively before and after centrifugation. The results are presented in Table 4 below.
    Unit Viscosity (V-Funnel) second Fluidity mm compactness Rc to28 days MPa Rift Reference <3 > 150 10-11 50 0 Example 1 1.35 170 11 65 0
    | Example 2 | 1.9 | 160 | 10.5 | 74 | 0 |
    Table 4: Physical properties of fresh and hardened mortar formulations.
    The viscosity and the fluidity of the mortar were determined respectively by measuring the flow time at V-Funnel, as defined by standard EN 12350-9 (November 2010) and by measuring spreading according to standard NF EN 12706 (May 2000). The results show that the mortars according to the first and second embodiments make it possible to satisfy the flow criteria required for the production of pipe coatings.
    The compactness measurements in the fresh state after centrifugation were carried out in accordance with a sinking resistance method with a pocket penetrometer. The results show that the mortars according to the first and second embodiment make it possible to obtain coatings whose compactness is comparable to the reference coating.
    Mechanical performance has been determined in accordance with standard NF EN 196-1 (September 2016). It appears that at 28 days the mechanical resistance to compression (Rc) of the coatings according to the first and second embodiment is significantly higher than the 50 MPa recommended for pipe coatings in accordance with standard NF EN 545 (December 2010).
    Crack resistance properties were determined by studying the removal, first, of ring-shaped mortar samples molded around a metal core and second, of coatings of pipe sections one meter long. At the end of the 28 days of wet curing, the results show that the coatings according to the first and the second embodiment show no cracks for the two types of samples.
    After 28 days, the prototype pipes have been tested for leaching according to standard EN 14944-3 (March 2008) "influence of cement-based products on water intended for human consumption". The protocol used corresponds to tests for pipes with a nominal diameter of 80 mm (DN 80). The limit of leached aluminum is a function of the nominal diameter of the pipe. In the case of pipes with a nominal diameter of 80 mm, the limit is 45 pg / l. The results of the aluminum migration tests for the three coating formulations are presented in Figures 3 to 5.
    In the three figures 3 to 5, the quantities of leached aluminum are shown in pg / l for the three migration tests 1, 2 and 3 recommended by standard EN 14944-3. They are noted M1, M2, M3 on the abscissa. In each of these figures, curve C3 represents the regulatory limit of 45 pg / L
    In FIG. 3, the curves C4, C5 and C6 correspond to three reference coatings deposited in three pipes and the composition of which is specified in the table
    3.
    In Figure 4, curves C7 and C8 correspond to two coatings according to Example 1 of Table 3 deposited in two pipes.
    In FIG. 5, the curves C9 and C10 correspond to two coatings according to Example 2 of Table 3 deposited in two pipes.
    The following table 5 shows the average concentration of aluminum released during migration. The averages expressed in table 5 were carried out by considering all the pipes tested for each type of coating and by averaging the results obtained for the three migrations.
    Reference Example 1 Example 2 Average aluminum concentration (wg / l) 102 45 <12 Reduced aluminum leaching 0% 56% > 88%
    Table 5: Average concentration of aluminum leached according to standard EN-14944 and reduction in the leaching of aluminum obtained with the new formulations.
    As can be seen, the average concentration of released aluminum is 102 pg / l for the reference coatings, 45 pg / l for the coatings according to the first example, and less than 12 pg / l for the coatings according to the second. example. Thus, it can be seen that the coatings according to the first example reduce the leaching of aluminum by 56% compared to the reference, while those according to the second example reduce this leaching by more than 88%.
    The two cementitious compositions (first and second examples) described above are suitable for the manufacture of interior coatings for pipe or tank elements intended in particular for the distribution, supply and storage of drinking water. These coatings make it possible to significantly reduce the leaching of aluminum, and therefore for example to meet future regulatory criteria on the migration of this element in drinking water. In addition to their good environmental properties, these new coatings have a level of durability much higher than that of coatings made from conventional Portland cement.
    权利要求:
    Claims (11)
    [1" id="c-fr-0001]
    1, - Coated pipe or tank element (10) comprising:
    - a raw pipe or tank element (12) made of ductile iron, steel or concrete, and
    - an interior coating (18) located on an interior wall (14) of the raw pipe or tank element (12), the interior coating (18) being obtainable by application to the interior wall (14) a mortar comprising a binder, characterized in that the binder comprises one of:
    a first composition comprising a mixture of Portland cement CEM I SR and blast furnace slag, the mass proportion of Portland cement CEM I SR in said mixture being between 5% and 64%,
    a second composition comprising a mixture of CEM III / B cement and microsilica, or a mixture of Portland cement CEM I SR and microsilica, the mass proportion of CEM III / B cement or Portland cement CEM I SR in said mixture being between 50% and 94%, and
    - mixtures of the first composition and the second composition.
    [2" id="c-fr-0002]
    2, - coated pipe or reservoir element (10) according to claim 1, in which the binder comprises a mixture of Portland cement CEM I SR, slag and microsilica, the mass proportion of Portland cement CEM I SR in said mixture being between 30% and 60%, preferably between 40% and 60%, and even more preferably between 50% and 60%, the mass proportion of the slag in said mixture being between 65% and 5%, preferably between 50% and 10%, and even more preferably between 30% and 10%, and the mass proportion of microsilica in said mixture being between 5% and 35%, preferably between 10% and 30%, and so even more preferred between 20% and 30%.
    [3" id="c-fr-0003]
    3, - coated pipe or reservoir element (10) according to claim 1 or 2, in which the Portland cement CEM I SR of the first composition or of the second composition or of their mixtures is a CEM I SR5, preferably a CEM I SR3, and even more preferably a CEM I SRO.
    [4" id="c-fr-0004]
    4. - coated pipe or reservoir element (10) according to any one of claims 1 to 3, in which the mass proportion of Portland cement CEM I SR in said mixture of the first composition is between 20% and 64% , preferably between 25% and 50%, and even more preferably between 25% and 34%.
    [5" id="c-fr-0005]
    5. - coated pipe or tank element (10) according to any one of claims 1 to 4, in which the mass proportion of CEM III / B cement or Portland CEM I SR cement in said mixture of the second composition is between 60% and 90%, preferably between 70% and 80%.
    [6" id="c-fr-0006]
    6. - coated pipe or reservoir element (10) according to any one of claims 1 to 5, in which the mortar also comprises fillers, in a mass ratio (S / L) relative to the binder between 0 , 5 and 5, preferably between 1 and 4, and even more preferably between 1.5 and 3.
    [7" id="c-fr-0007]
    7. - coated pipe or reservoir element (10) according to claim 6, in which the fillers are filler, sand and / or gravel, preferably of siliceous or calcareous nature, at least 95% by mass of the fillers having a diameter less than or equal to 8 mm.
    [8" id="c-fr-0008]
    8. - coated pipe or reservoir element (10) according to any one of claims 1 to 7, in which the mortar also comprises water, in a mass ratio (E / L) of water by ratio of the binder of between 0.2 and 1, preferably between 0.3 and 0.5, and even more preferably between 0.35 and 0.45.
    [9" id="c-fr-0009]
    9. - coated pipe or tank element (10) according to any one of claims 1 to 8, in which:
    the binder comprises the first composition, and the mortar also comprises one or more superplasticizer (s), in a mass ratio (Sp / L) of superplasticizer (s) relative to the binder of between 0.0005 and 0.1, preferably between 0.001 and 0.05, and even more preferably between 0.002 and 0.03, or
    the binder comprises the second composition, and the mortar also comprises one or more superplasticizer (s), in a mass ratio (Sp / L) of superplasticizer (s) relative to the binder of between 0.005 and 0.1, preferably between 0.001 and 0.08, and even more preferably between 0.005 and 0.05.
    [10" id="c-fr-0010]
    10. - coated pipe or reservoir element (10) according to claim 9, wherein said one or more superplasticizer (s) comprises a polycarboxylate solution with a dry extract of 10% to 50%, preferably 20% to 40% and even more preferably from 25% to 35%.
    [11" id="c-fr-0011]
    11, - coated pipe or tank element (10) according to any one of claims 1 to 10, in which the mortar further comprises one or more adjuvant (s), in a mass ratio (A / L) of adjuvant (s) with respect to the binder of between 0.001 and 0.05, preferably between 0.005 and 0.04, and even more preferably between
    10 0.01 and 0.03.
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    CH525165A|1972-07-15|Cement compsns contng hardenable resin-
    FR2810662A1|2001-12-28|WASTE CONTAINMENT CONCRETE
    同族专利:
    公开号 | 公开日
    WO2019215121A1|2019-11-14|
    FR3080904B1|2020-05-22|
    BR112020021999A2|2021-01-26|
    EP3791099A1|2021-03-17|
    CN112105859A|2020-12-18|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US5735947A|1995-09-22|1998-04-07|Lafarge Canada Inc.|Cement with air-cooled slag and silica fume|
    US20050160946A1|2003-01-31|2005-07-28|Comrie Douglas C.|Cementitious materials including stainless steel slag and geopolymers|
    WO2007107763A2|2006-03-21|2007-09-27|Halliburton Energy Services, Inc.|Low heat of hydration cement compostions and methods of using same|
    US20110283516A1|2010-05-24|2011-11-24|Saudi Aramco|Economical Heavy Concrete Weight Coating for Submarine Pipelines|CN112142495A|2020-09-29|2020-12-29|新兴铸管股份有限公司|Inorganic anti-corrosion lining of nodular cast iron pipe containing glass beads and manufacturing method|
    CN112159181A|2020-09-29|2021-01-01|新兴铸管股份有限公司|Anticorrosive lining of nodular cast iron pipe for conveying drinking water and manufacturing method|FR2901268B1|2006-05-17|2008-07-18|Lafarge Sa|CONCRETE WITH LOW CEMENT CONTENT|
    FR3022541A1|2014-06-20|2015-12-25|Lafarge Sa|ULTRA HIGH PERFORMANCE NON-AUTOPLACING CONCRETE|
    法律状态:
    2019-04-10| PLFP| Fee payment|Year of fee payment: 2 |
    2019-11-08| PLSC| Search report ready|Effective date: 20191108 |
    2020-04-14| PLFP| Fee payment|Year of fee payment: 3 |
    2021-04-12| PLFP| Fee payment|Year of fee payment: 4 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1853916A|FR3080904B1|2018-05-07|2018-05-07|PIPE OR TANK ELEMENT WITH INTERNAL CEMENT COATING|
    FR1853916|2018-05-07|FR1853916A| FR3080904B1|2018-05-07|2018-05-07|PIPE OR TANK ELEMENT WITH INTERNAL CEMENT COATING|
    PCT/EP2019/061634| WO2019215121A1|2018-05-07|2019-05-07|Drinking water pipe or reservoir element with cementitious inner lining|
    BR112020021999-1A| BR112020021999A2|2018-05-07|2019-05-07|pipe or potable water tank element with internal cementitious lining|
    EP19722608.7A| EP3791099A1|2018-05-07|2019-05-07|Drinking water pipe or reservoir element with cementitious inner lining|
    CN201980030946.3A| CN112105859A|2018-05-07|2019-05-07|Drinking water pipe or reservoir element with cement-based inner lining|
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